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鋰電池的可用容量和剩余容量是什么?

2022-09-08

鋰電池

一、鋰電池的可用容量

可用容量可能只能用80-90%。鋰電池的化學(xué)容量是在電流很小的時(shí)候測(cè)量的,它更多的是由電池本身的特性決定的。實(shí)際的,鋰電池在實(shí)際使用過(guò)程中,因?yàn)橛幸欢ǖ姆烹婋娏?,放電曲線將低于開(kāi)路電壓曲線,這條曲線可以看出,由于電池內(nèi)阻的存在,實(shí)際放電曲線是藍(lán)色的,藍(lán)色曲線和紅色曲線對(duì)應(yīng)于Quse,實(shí)際上是指電池的可用容量。在這條曲線中,我們發(fā)現(xiàn)由于電池內(nèi)阻的存在,這條曲線的位置向下移動(dòng),所以放電會(huì)更早到達(dá)放電終止電壓,也就是更早到達(dá)EDV。所以Quse一般小于Qmax。

二、鋰電池的剩余容量

剩余容量是指電池在當(dāng)前狀態(tài)下放入EDV的容量,即終止放電電壓。在圖中,電流狀態(tài)A在給定的電流下被釋放。當(dāng)放電達(dá)到3.0V時(shí),對(duì)應(yīng)的剩余容量記為R1。如果在狀態(tài)A的情況下,釋放了更大的電流,這條曲線的位置會(huì)比開(kāi)路電壓略低,也會(huì)比RM1小電流放電所對(duì)應(yīng)的位置略低,那么此時(shí)得到的剩余容量為RM2。RM2和RM1的區(qū)別在于使用的放電電流不同。放電電流越大,曲線位置越低,剩余容量越小。因此,電池的剩余容量與放電速率有關(guān),不同電流下電池的剩余容量是不同的。


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