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如何提高聚合物鋰電池的安全性?

2022-06-16

聚合物鋰電池

隨著科技的進(jìn)步,電子設(shè)備的使用,使得聚合物鋰電池的安全性要求更高。那么我們?nèi)绾翁岣呔酆衔镤囯姵氐陌踩阅兀?/p>

1、安全閥的開(kāi)啟壓力和靈敏度是影響鋰電池安全的重要因素,可以在一定程度上降低爆炸傷害。

2、在電解液中加入聚合物單體分子,當(dāng)充電電壓超過(guò)極限時(shí),電極表面聚合成膜,電化學(xué)氧化聚合反應(yīng)封閉電極表面,阻斷電池反應(yīng)防止不安全行為。

3、隔膜PP/PE/PP優(yōu)于PE和PP;當(dāng)鋰電池的溫度升高時(shí),隔膜中間層PE微孔先閉合,阻斷電流通過(guò),起到安全作用。

4、結(jié)構(gòu)設(shè)計(jì)是指電池內(nèi)部的安全隔離措施,包括正極和負(fù)極、膜片寬度、固定限位片、負(fù)極片兩端粘接、芯粘接等。

那么當(dāng)聚合物鋰電池發(fā)生故障時(shí),會(huì)有什么情況發(fā)生呢?

1、短路:電池充滿(mǎn)電后,對(duì)正極和負(fù)極進(jìn)行短路,導(dǎo)線電阻小于50mQ。測(cè)試結(jié)果:電池短路后不著火、不爆炸。

2、過(guò)充:電池在3C倍增器和5V電壓條件下過(guò)充,電池不會(huì)爆炸或著火。

3、熱沖擊:鋰電池充滿(mǎn)電后,在恒溫箱中以5℃/min的速度加熱至150℃,保存30min。測(cè)試結(jié)果為,外殼膨脹和發(fā)熱,但電池不起火,不爆炸。

4、自由跌落:從X、Y、Z六個(gè)面在1000mm高度各下降2次,下降后電池電壓、內(nèi)阻、容量正常,無(wú)發(fā)熱、鼓泡等缺陷。

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