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鈷酸鋰電池的工作原理和化學(xué)方程式

2022-11-16

鈷酸鋰電池

鈷酸鋰電池的鈷酸鋰化學(xué)式為LiCoO2,是一種無機(jī)化合物,一般用作鋰離子電池的正極材料。LiCoO2基本采用了目前商用鋰離子電池中層狀結(jié)構(gòu)的鋰離子二次電池正極材料 (鈷酸鋰) 的液相合成工藝。它以聚乙烯醇 (PVA) 或聚乙二醇 (PEG) 水溶液為溶劑,將鋰鹽和鉆鹽分別溶于PVA或PEG水溶液中,混合溶液加熱濃縮形成凝膠,并對生成的凝膠進(jìn)行加熱分解,然后高溫煅燒,將燒結(jié)后的粉末進(jìn)行研磨、篩分,得到鈷酸鋰粉。

LiCoO2廣泛用于大功率鋰離子電池。層狀LiCoO2鋰離子在CoO2原子致密層層之間二維運動,具有工作電壓高、充放電電壓穩(wěn)定、比能量高、循環(huán)性能好等優(yōu)點。

鈷酸鋰電池充放電過程中發(fā)生的反應(yīng):

充電過程中的反應(yīng):

正極:LiCoO2=Li1-xCo02+xLi++xe-

負(fù)極:6C+xLi++xe-=LixC6

放電過程中的反應(yīng):

正極:Li1-xCoO2+xLi++xe-=LiCoO2

負(fù)極:LixC6=6C+xLi++xe-


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