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聚合物鋰離子電池的新型充電方法

2022-08-27

聚合物鋰離子電池

目前,聚合物鋰離子電池主要采用限壓限流的充電方式。恒流(CC)充電初期,電池接受能力強(qiáng)。隨著充電過程的不斷進(jìn)行,極化效應(yīng)增強(qiáng),溫升加劇,電壓升高。在恒壓階段有涓流充電,大約用30%的時(shí)間充10%的電,電流強(qiáng)度減小,溫升不增加。

在此過程中,考慮聚合物鋰離子電池的總電壓或平均電壓。事實(shí)上,單體電池的電壓一直較高,相對(duì)于組內(nèi)其他電池已經(jīng)進(jìn)入充電階段。同樣,在放電時(shí),電池中也有一組放電,過充和過放電對(duì)電池的損傷是致命的,區(qū)別只是過充產(chǎn)生大量氣體,容易自燃爆炸;過放外觀變化緩慢,但故障率非???,在正常使用時(shí)應(yīng)嚴(yán)格避免。

為此,提出了一種新的鋰電池充電方法——并聯(lián)控制與平衡管理,該方法可以對(duì)每個(gè)電池芯分別進(jìn)行充放電管理和平衡控制。這種動(dòng)態(tài)平衡集放電平衡和充電平衡的優(yōu)點(diǎn)于一體。雖然單體電池在初始容量、電壓、內(nèi)阻等方面存在差異,但在工作中能夠保證相對(duì)充放電強(qiáng)度和深度的一致性,并逐漸達(dá)到共同的壽命終點(diǎn)。這種方法特別適用于大電流放電。


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