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掛卡鋰電池正極材料的結(jié)構(gòu)特點(diǎn)

2022-05-11

掛卡鋰電池

掛卡鋰電池通常是指采用鎳鈷錳酸鋰或鎳鈷鋁酸鋰作為正極材料的鋰電池,一般使用鎳鹽、錳鹽等作為正極材料的原料,其中鎳鈷錳的比例可以根據(jù)實(shí)際需要來調(diào)整,這種材料做的掛卡鋰電池相對于鈷酸鋰電池的安全性高。

1999年Liu等首次報(bào)道了層狀鎳鉆錳三元過渡金屬復(fù)合氧化物,具有循環(huán)性能好、比容量高、安全性高等特性。在2001年,T.Ohzuku等首次合成了層狀NaFeO、LiNiuaCou3Mn/30,具有優(yōu)異的性能,這項(xiàng)研究引起了人們的特別關(guān)注。層狀鎳鉆錳三元復(fù)合材料在一定程度上集成了LiCo02、LiNiO2和LiMnO的優(yōu)點(diǎn),彌補(bǔ)了其不足,提高了材料性能,降低了成本。

掛卡鋰電池正極材料的結(jié)構(gòu)特點(diǎn):

1、層狀或隧道狀結(jié)構(gòu)有利于鋰離子的脫包,且在鋰離子脫包過程中結(jié)構(gòu)沒有變化,確保電極具有良好的可逆性能;

2、電極具有高容量,由于大量的鋰離子嵌入和釋放,電極反應(yīng)的自由能不改變,確保掛卡鋰電池的放電電壓的穩(wěn)定性;

3、鋰離子具有較大的擴(kuò)散系數(shù),以使電池具有良好的快速充放電性能。


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